Microwave-assisted synthesis of calcium phosphate nanowhiskers

被引：54

作者：

Jalota, S ^{[1
]}

Tas, AC ^{[1
]}

Bhaduri, SB ^{[1
]}

机构：

[1] Clemson Univ, Sch Mat Sci & Engn, Clemson, SC 29634 USA

来源：

JOURNAL OF MATERIALS RESEARCH | 2004年 / 19卷 / 06期

关键词：

D O I：

10.1557/JMR.2004.0230

中图分类号：

T [工业技术];

学科分类号：

08 [工学];

摘要：

Calcium phosphate [single-phase hydroxyapatite (HA), single-phase tricalcium phosphate (TCP), and biphasic HA-TCP] nanowhiskers and/or powders were produced by using a novel microwave-assisted "combustion synthesis (auto ignition)/molten salt synthesis" hybrid route. This work is an example of our "synergistic processing" philosophy combining these three technologies while taking advantage of their useful aspects. Aqueous solutions containing NaNO3, Ca(NO3)(2).4H(2)O and KH2PO4 (with or without urea) were irradiated in a household microwave oven for 5 min at 600 watts of power. The as-synthesized precursors were then simply stirred in water at room temperature for 1 h to obtain the nanowhiskers or powders of the desired calcium phosphate bioceramics.

引用

页码：1876 / 1881

页数：6

共 35 条

[1]

Molten salt synthesis of nitrate-exchanged magnesium and aluminum sodalites [J].

Afanasiev, P .

CHEMISTRY OF MATERIALS, 2001, 13 (02) :459-461

[2]

EFFECT OF ALKALI-METAL CATIONS ON THE PROPERTIES OF ZIRCONIA PREPARED IN MOLTEN NITRATES [J].

AFANASIEV, P ;

GEANTET, C .

MATERIALS CHEMISTRY AND PHYSICS, 1995, 41 (01) :18-27

[3]

MOLTEN-SALT SYNTHESIS OF SINGLE MAGNETIC DOMAIN BAFE12O19 AND SRFE12O19 CRYSTALS [J].

ARENDT, RH .

JOURNAL OF SOLID STATE CHEMISTRY, 1973, 8 (04) :339-347

[4]

HYDROXYAPATITE CRYSTAL-GROWTH ON CALCIUM HYDROXYAPATITE CERAMICS [J].

ASADA, M ;

MIURA, Y ;

OSAKA, A ;

OUKAMI, K ;

NAKAMURA, S .

JOURNAL OF MATERIALS SCIENCE, 1988, 23 (09) :3202-3205

[5]

Formation of hydroxyapatite precursors at 37 °C in urea- and enzyme urease-containing body fluids [J].

Bayraktar, D ;

Tas, AC .

JOURNAL OF MATERIALS SCIENCE LETTERS, 2001, 20 (05) :401-403

[6]

Use reflectance FT-IR spectroscopic study of interactions of α-Al2O3/molten NaNO3 coexisting systems [J].

Beleke, AB ;

Mizuhata, M ;

Deki, S .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2003, 5 (10) :2089-2095

[7]

Microwave dielectric properties of Ca[(Li1/3Nb2/3)1-xMx]O3-δ (M = Sn, Ti) ceramics [J].

Choi, JW ;

Kang, CY ;

Yoon, SJ ;

Kim, HJ ;

Jung, HJ ;

Yeon, KH .

JOURNAL OF MATERIALS RESEARCH, 1999, 14 (09) :3567-3570

[8]

Bhaduri S. B., 1999, Ceramic Engineering and Science Proceedings, V20, P227

[9]

Nanosized CeO2 powders obtained by flux method [J].

Bondioli, F ;

Corradi, AB ;

Leonelli, C ;

Manfredini, T .

MATERIALS RESEARCH BULLETIN, 1999, 34 (14-15) :2159-2166

[10]

Current state of the art of biphasic calcium phosphate bioceramics [J].

Daculsi, G ;

Laboux, O ;

Malard, O ;

Weiss, P .

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN MEDICINE, 2003, 14 (03) :195-200

← 1 2 3 4 →