Phase behavior of ionic liquid-LiX mixtures:: Pyrrolidinium cations and TFSI- anions

被引：267

作者：

Henderson, WA ^{[1
]}

Passerini, S ^{[1
]}

机构：

[1] ENEA, Italian Natl Agcy New Technol Energy & Environm, Casaccia Res Ctr, I-00060 Rome, Italy

来源：

CHEMISTRY OF MATERIALS | 2004年 / 16卷 / 15期

关键词：

D O I：

10.1021/cm049942j

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 [物理化学]; 081704 [应用化学];

摘要：

Phase diagrams are reported for mixtures between bis(trifluoromethanesulfonyl)imide (TFSI-) salts containing Li+ and N-alkyl-N-methylpyrrolidinium (PYR1R+) cations. The latter salts readily form both room temperature ionic liquids and plastic crystalline phases. Mixed salt crystalline phases are found which are likely to influence the performance of such mixed salt systems when utilized as electrolytes for electrochemical devices as well as give insight into ionic liquid-solute interactions.

引用

页码：2881 / 2885

页数：5

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