Nanocrystal Photovoltaic Paint Sprayed With a Handheld Airbrush

被引:9
作者
Javier, Artjay [1 ]
Foos, Edward E. [1 ]
机构
[1] USN, Res Lab, Washington, DC 20375 USA
关键词
Fabrication; nanotechnology; photovoltaic (PV) cells; thin films; SOLAR-CELLS; SHAPE-CONTROL; POLYMER; HETEROJUNCTION; FILMS;
D O I
10.1109/TNANO.2009.2020796
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
A complete photovoltaic cell was fabricated using only a handheld airbrush, dilute solutions of CdSe and CdTe nanorods, commercially available silver paint, and transparent-conducting-electrode-coated glass. Produced and stored under ambient conditions, these fully functioning solar cells are stable for months. As a heterojunction cell, the migration of carriers within the CdTe and CdSe layers is polarity-dependent, which directly contributes to the photoinduced voltaic cell response observed. The suitability of a handheld airbrush to create high-quality films by varying solution concentration, air pressure, and nanorod surface functionalization was explored. Notably, ultrasmooth surfaces comparable to spin-coated quality films can be formed from 20 to 500 nm thickness, with continuous, uninterrupted optical domains such that strong light diffraction is observed. While current estimated efficiency is low(<0.01%), this method demonstrates the potential of solar cells that can be incorporated into a variety of devices of unconventional size or design.
引用
收藏
页码:569 / 573
页数:5
相关论文
共 20 条
[1]   Performance of bulk heterojunction photovoltaic devices prepared by airbrush spray deposition [J].
Green, R. ;
Morfa, A. ;
Ferguson, A. J. ;
Kopidakis, N. ;
Rumbles, G. ;
Shaheen, S. E. .
APPLIED PHYSICS LETTERS, 2008, 92 (03)
[2]   Air-stable all-inorganic nanocrystal solar cells processed from solution [J].
Gur, I ;
Fromer, NA ;
Geier, ML ;
Alivisatos, AP .
SCIENCE, 2005, 310 (5747) :462-465
[3]   Controlled assembly of hybrid bulk-heterojunction solar cells by sequential deposition [J].
Gur, Ilan ;
Fromer, Neil A. ;
Alivisatos, A. Paul .
JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (50) :25543-25546
[4]   Hybrid solar cells with prescribed nanoscale morphologies based on hyperbranched semiconductor nanocrystals [J].
Gur, Ilan ;
Fromer, Neil A. ;
Chen, Chih-Ping ;
Kanaras, Antonios G. ;
Alivisatos, A. Paul .
NANO LETTERS, 2007, 7 (02) :409-414
[5]   Hybrid nanorod-polymer solar cells [J].
Huynh, WU ;
Dittmer, JJ ;
Alivisatos, AP .
SCIENCE, 2002, 295 (5564) :2425-2427
[6]   Controlling the morphology of nanocrystal-polymer composites for solar cells [J].
Huynh, WU ;
Dittmer, JJ ;
Libby, WC ;
Whiting, GL ;
Alivisatos, AP .
ADVANCED FUNCTIONAL MATERIALS, 2003, 13 (01) :73-79
[7]   Efficient tandem polymer solar cells fabricated by all-solution processing [J].
Kim, Jin Young ;
Lee, Kwanghee ;
Coates, Nelson E. ;
Moses, Daniel ;
Nguyen, Thuc-Quyen ;
Dante, Mark ;
Heeger, Alan J. .
SCIENCE, 2007, 317 (5835) :222-225
[8]   Structural colors in nature: The role of regularity and irregularity in the structure [J].
Kinoshita, S ;
Yoshioka, S .
CHEMPHYSCHEM, 2005, 6 (08) :1442-1459
[9]   Structural, optical and electrical properties of self-assembled films of PbSe nanocrystals treated with 1,2-ethanedithiol [J].
Luther, Joseph M. ;
Law, Matt ;
Song, Qing ;
Perkins, Craig L. ;
Beard, Matthew C. ;
Nozik, Arthur J. .
ACS NANO, 2008, 2 (02) :271-280
[10]   Synthesis of soluble and processable rod-, arrow-, teardrop-, and tetrapod-shaped CdSe nanocrystals [J].
Manna, L ;
Scher, EC ;
Alivisatos, AP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (51) :12700-12706