Podocarpane-to-spongian skeleton conversion. Synthesis of (+)-isoagatholactone and (-)-spongia-13(16),14-diene

被引：20

作者：

Abad, A

Agullo, C

Arno, M

Marin, ML

Zaragoza, RJ

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1996年 / 17期

关键词：

D O I：

10.1039/p19960002193

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A stereoselective synthesis of the spongian diterpenes (+)-isoagatholactone 5 and (-)-spongia-13(16),14-diene 6 is achieved starting from (+)-podocarp-8(14)-en-13-one 3 (R = H) via the common intermediate beta-hydroxy ketone 13.

引用

页码：2193 / 2199

页数：7

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