Cuprophilicity? a rare example of a ligand-unsupported Cu-I-Cu-I interaction

被引：90

作者：

Siemeling, U

Vorfeld, U

Neumann, B

Stammler, HG

机构：

[1] Fakultät für Chemie, Universität Bielefeld, D-33615 Bielefeld

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 18期

关键词：

D O I：

10.1039/a702793a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of 1,1'-bis(2-pyridyl)octamethylferrocene (L) with [Cu(NCMe)(4)]BF4 in CH2Cl2 affords [CuL][CuCl2], the structure of which is determined by a single-crystal X-ray diffraction study; this reveals a remarkably short ligand-unsupported Cu-I-Cu-I contact of 281.0(2) pm.

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页码：1723 / 1724

页数：2

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