Synthesis of a homoleptic niobium(V) thiolate complex and the preparation of niobium sulfide via thio "sol-gel" and vapor phase thin-film experiments

被引：13

作者：

Carmalt, CJ

Dinnage, CW

Parkin, IP

White, AJP

Williams, DJ

机构：

[1] UCL, Christopher Ingold Labs, Dept Chem, London WC1H 0AJ, England

[2] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

来源：

INORGANIC CHEMISTRY | 2002年 / 41卷 / 14期

关键词：

D O I：

10.1021/ic020097l

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of [Nb(NMe2)(5)] with 10 equiv of 2,6-Me2C6H3SH in toluene results in the formation of red crystals of [Nb(SC6H3Me2-2,6)(5)]. Crystal structure analysis of [Nb(SC6H3Me2-2,6)(5)] showed that the niobium center adopts a distorted trigonal bipyramical geometry. Niobium disulfide, NbS2, has been successfully prepared via a thio "sol-gel" process using [Nb(SC6H3Me2-2,6)(5)] as the metal source. In contrast, vapor phase thin-film studies revealed that [Nb(SC6H3Me2-2,6)(5)] functions as a single-source precursor to NbS films.

引用

页码：3668 / 3672

页数：5

共 31 条

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