One-pot enantioselective formation of eight-membered rings from alkenyl Fischer carbene complexes and ketone enolates

被引：29

作者：

Barluenga, J ^{[1
]}

Diéguez, A ^{[1
]}

Rodríguez, F ^{[1
]}

Flórez, J ^{[1
]}

Fañanás, FJ ^{[1
]}

机构：

[1] Univ Oviedo, Inst Univ Quim Organomet Enrique Moles, Unidad Asociada CSIC, E-33071 Oviedo, Spain

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 31期

关键词：

D O I：

10.1021/ja0264551

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Eight-membered carbocycles with up to five new stereogenic centers are enantioselectively obtained following a one-pot procedure that involves the coupling of three components: an alkenyl Fischer carbene complex, a ketone enolate, and allyl lithium. Copyright © 2002 American Chemical Society.

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收藏

页码：9056 / 9057

页数：2

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