Asymmetric aza-Henry reaction of N-tosyl imine

被引：34

作者：

Gao, Feifeng ^{[1
]}

Zhu, Jiang ^{[1
]}

Tang, Yong ^{[1
]}

Deng, Minzhi ^{[1
]}

Qian, Changtao ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

CHIRALITY | 2006年 / 18卷 / 09期

关键词：

N-tosyl imines; diethylzinc; reduction; coordination; aza-Henry reaction; nitro-Mannich reaction;

D O I：

10.1002/chir.20315

中图分类号：

R914 [药物化学];

学科分类号：

100701 ;

摘要：

An efficient stereoselective aza-Henry reaction of N-tosyl imine, catalyzed by the coordination of diethylzinc with a chiral semi-aza-crown ligand, with moderate to high ee (up to 83%) is reported.

引用

页码：741 / 745

页数：5

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