Supramolecular polymeric macrocyclic receptors -: Hybrid carrier versus channel transporters in bulk liquid membranes

被引:42
作者
Barboiu, M [1 ]
机构
[1] IEM, CNRS, UMR 5635, F-34095 Montpellier, France
关键词
crown compounds; dynamic self-assembly; liquid membranes; macrocyclic carrier;
D O I
10.1023/B:JIPH.0000031126.58442.f4
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis of heteroditopic macrocyclic ureido-receptors is described. NMR studies show the formation of self-organized oligomeric superstructures. Membrane transport experiments show a direct relation between the self-assembling and the transport properties of these molecular information transfer devices. The self-organization of these receptors may provide the first evidence for the possible hybrid transport carrier versus channel mechanisms in liquid membranes.
引用
收藏
页码:133 / 137
页数:5
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