Three-dimensional metal-organic framework with (3,4)-connected net, synthesized from an ionic liquid medium

被引:222
作者
Dybtsev, DN
Chun, H
Kim, K
机构
[1] Pohang Univ Sci & Technol, Dept Chem, Div Mol & Life Sci, Natl Creat Res Initiat Ctr Smart Supramol, Pohang 790784, South Korea
[2] Russian Acad Sci, Inst Inorgan Chem, Novosibirsk 630090, Russia
关键词
D O I
10.1039/b403001j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new 3D metal-organic framework with a (3,4)-connected network topology is synthesized from an ionic liquid medium; its highly symmetrical structure comprises doubly interpenetrating nets with the cubic-C3N4 topology.
引用
收藏
页码:1594 / 1595
页数:2
相关论文
共 41 条
[1]   A cubic (3,4)-connected net with large cavities in solvated [Cu-3(tpt)(4)](ClO4)(3) (tpt=2,4,6-tri(4-pyridyl)-1,3,5-triazine) [J].
Abrahams, BF ;
Batten, SR ;
Hamit, H ;
Hoskins, BF ;
Robson, R .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (15) :1690-1692
[2]   Topology of interpenetration [J].
Batten, SR .
CRYSTENGCOMM, 2001, (18)
[3]   Templated assembly of sulfide nanoclusters into Cubic-C3N4 type framework [J].
Bu, XH ;
Zheng, NF ;
Li, YQ ;
Feng, PY .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (20) :6024-6025
[4]   A route to high surface area, porosity and inclusion of large molecules in crystals [J].
Chae, HK ;
Siberio-Pérez, DY ;
Kim, J ;
Go, Y ;
Eddaoudi, M ;
Matzger, AJ ;
O'Keeffe, M ;
Yaghi, OM .
NATURE, 2004, 427 (6974) :523-527
[5]   Interwoven metal-organic framework on a periodic minimal surface with extra-large pores [J].
Chen, BL ;
Eddaoudi, M ;
Hyde, ST ;
O'Keeffe, M ;
Yaghi, OM .
SCIENCE, 2001, 291 (5506) :1021-1023
[6]   A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n [J].
Chui, SSY ;
Lo, SMF ;
Charmant, JPH ;
Orpen, AG ;
Williams, ID .
SCIENCE, 1999, 283 (5405) :1148-1150
[7]   From curiosities to commodities: ionic liquids begin the transition [J].
Davis, JH ;
Fox, PA .
CHEMICAL COMMUNICATIONS, 2003, (11) :1209-1212
[8]   Microporous manganese formate: A simple metal-organic porous material with high framework stability and highly selective gas sorption properties [J].
Dybtsev, DN ;
Chun, H ;
Yoon, SH ;
Kim, D ;
Kim, K .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (01) :32-33
[9]   Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage [J].
Eddaoudi, M ;
Kim, J ;
Rosi, N ;
Vodak, D ;
Wachter, J ;
O'Keeffe, M ;
Yaghi, OM .
SCIENCE, 2002, 295 (5554) :469-472
[10]   Modular chemistry: Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks [J].
Eddaoudi, M ;
Moler, DB ;
Li, HL ;
Chen, BL ;
Reineke, TM ;
O'Keeffe, M ;
Yaghi, OM .
ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (04) :319-330