Eu2+ ions and CaF2-containing transparent glass-ceramics

被引：100

作者：

Fu, J

Parker, JM

Flower, PS

Brown, RM

机构：

[1] Univ Sheffield, Dept Mat Engn, Sheffield S1 3JD, S Yorkshire, England

[2] Rutherford Appleton Lab, CLRC, Particle Phys Dept, Didcot OX11 0QX, Oxon, England

来源：

MATERIALS RESEARCH BULLETIN | 2002年 / 37卷 / 11期

关键词：

glass; optical materials; X-ray diffraction; optical properties;

D O I：

10.1016/S0025-5408(02)00862-0

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Transparent glass-ceramics have been prepared by heat-treating 45SiO(2)-20Al(2)O(3)-10CaO-25CaF(2) glasses doped with Eu2+ ions (in mol%). The precipitated crystalline phase in the glass-ceramics was CaF2. TEM observation showed the precipitated crystalline phase had a size of 11-18 nm and dispersed in the amorphous phase without clustering. Fluorescence measurements showed that Eu2+ ions entered into the CaF2 crystalline phase and gave a much stronger emission in the glass-ceramics than in the corresponding glass. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：1843 / 1849

页数：7

共 8 条

[1]

[Anonymous], 1995, J APPL PHYS

[2] Future hosts for fast and high light output cerium-doped scintillator [J].