Formation of a tetrahedral Tl-4 cluster directed by a novel homoscorpionate ligand

被引：36

作者：

Rheingold, AL ^{[1
]}

LiableSands, LM ^{[1
]}

Trofimenko, S ^{[1
]}

机构：

[1] UNIV DELAWARE,DEPT CHEM & BIOCHEM,NEWARK,DE 19716

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 17期

关键词：

D O I：

10.1039/a703349d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The thallium complex of a novel ligand, hydrotris(3-cyclopropylpyrazol-1-yl)borate, forms a stable tetramer, [T1(Tp(Cpr))](4), containing a perfect tetrahedron of T1 atoms, with each T1 in an octahedral environment.

引用

页码：1691 / 1692

页数：2

共 30 条

[1] SYNTHESIS AND CRYSTAL-STRUCTURE OF BIS[1,5-DITOLYLPENTAAZADIENIDO-THALLIUM(I)] AND BIS[1,3-DIPHENYLTRIAZENIDO-THALLIUM(I)] [J].

BECK, J ;

STRAHLE, J .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1986, 41 (11) :1381-1386

[2] INSERTION OF [VFE3S4]2+ AND [MOFE3S4]3+ CORES INTO A SEMIRIGID TRITHIOLATE CAVITAND LIGAND - REGIOSPECIFIC REACTIONS AT A VANADIUM SITE SIMILAR TO THAT IN NITROGENASE [J].

CIURLI, S ;

HOLM, RH .

INORGANIC CHEMISTRY, 1989, 28 (09) :1685-1690

[3] SUBSITE-DIFFERENTIATED ANALOGS OF NATIVE [4FE-4S]2+ CLUSTERS - PREPARATION OF CLUSTERS WITH 5-COORDINATE AND 6-COORDINATE SUBSITES AND MODULATION OF REDOX POTENTIALS AND CHARGE-DISTRIBUTIONS [J].

CIURLI, S ;

CARRIE, M ;

WEIGEL, JA ;

CARNEY, MJ ;

STACK, TDP ;

PAPAEFTHYMIOU, GC ;

HOLM, RH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (07) :2654-2664

[4] HYDRIDOTRIS(3-T-BUTYLPYRAZOLYL)BORATOTHALLIUM(I) - A SPECTROSCOPIC AND STRUCTURAL STUDY [J].

COWLEY, AH ;

GEERTS, RL ;

NUNN, CM ;

TROFIMENKO, S .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 365 (1-2) :19-22

[5] THE MOLECULAR AND CRYSTAL STRUCTURE OF THALLIUM (I) METHOXIDE [J].

DAHL, LF ;

DAVIS, GL ;

WAMPLER, DL ;

WEST, R .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1962, 24 (APR) :357-363

[6] The synthesis and structural characterization of the sterically demanding tris(3,5-di-t-butylpyrazolyl) hydroborato ligand, [Tp(Bu-2(t))]: A highly twisted, propeller-like, ligand system [J].

Dowling, CM ;

Leslie, D ;

Chisholm, MH ;

Parkin, G .

MAIN GROUP CHEMISTRY, 1995, 1 (01) :29-52

[7] STRUCTURE OF HYDRIDOTRIS[3-(PARA-TOLYL)PYRAZOLYL]BORATOTHALLIUM(I) [J].

FERGUSON, G ;

JENNINGS, MC ;

LALOR, FJ ;

SHANAHAN, C .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1991, 47 :2079-2082

[8] THE TRIS[3-(9-ANTHRYL)PYRAZOL-1-YL]HYDROBORATO LIGAND, [TP(ANT)] - COMPOSITIONAL DISORDER BETWEEN A VACANCY AND A CHAIN OF 3 ATOMS [J].

HAN, R ;

PARKIN, G ;

TROFIMENKO, S .

POLYHEDRON, 1995, 14 (03) :387-391

[9] Aggregation and redox-disproportionation in tripodal indium and thallium amides: First characterization of mixed-valent M(I)/M(II) compounds (M=In,Tl) [J].

Hellmann, KW ;

Gade, LH ;

Steiner, A ;

Stalke, D ;

Moller, F .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (1-2) :160-163

[10] A supramolecular motif in the solid-state structure of a difunctional thallium(I) amide defined by weak Tl center dot center dot center dot Tl attractions [J].

Hellmann, KW ;

Gade, LH ;

Fleischer, R ;

Stalke, D .

CHEMICAL COMMUNICATIONS, 1997, (06) :527-528

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