Two-step methane conversion to higher hydrocarbons: Comment on the relevance of metal-carbon bond strength

被引：8

作者：

Bradford, MCJ ^{[1
]}

机构：

[1] CeraMem Corp, Waltham, MA 02453 USA

来源：

JOURNAL OF CATALYSIS | 2000年 / 189卷 / 01期

关键词：

D O I：

10.1006/jcat.1999.2721

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Herein, data available in the literature for nonoxidative, two-step CH4 homologation over SiO2-supported transition metals are analyzed according to the principle of Sabatier, Volcano plots are constructed which provide empirical evidence to support the hypothesis that the metal-carbon bond strength is pivotal to determine catalyst efficiency, chain-growth probability, and selectivity to C-2(+) hydrocarbons. (C) 2000 Academic Press.

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页码：238 / 243

页数：6

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