Microfabricated palladium-silver alloy membranes and their application in hydrogen separation

被引:32
作者
Tong, HD
Gielens, FC
Gardeniers, JGE
Jansen, HV
van Rijn, CJM
Elwenspoek, MC
Nijdam, W
机构
[1] Univ Twente, MESA Res Inst Nanotechnol, NL-7500 AE Enschede, Netherlands
[2] Eindhoven Univ Technol, Dept Chem Engn & Chem, NL-5600 MB Eindhoven, Netherlands
[3] Aquamarijn Micro Filtrat BV, Zutphen, Netherlands
关键词
D O I
10.1021/ie034293r
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
A submicron-thick and defect-free palladium-silver (Pd-Ag) alloy membrane is manufactured using microfabrication technology. The microfabrication process creates a robust wafer-scale membrane module, which can easily be integrated into a holder with gastight connections. High separation fluxes of up to 4 mol of H-2/m(2.)s with a minimal selectivity of 1500 for H-2/He at 450 degreesC and 83 kPa of H-2 retentate pressure were obtained with this setup. The developed membrane technology has great potential for hydrogen purification and in. applications such as dehydrogenation.
引用
收藏
页码:4182 / 4187
页数:6
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