Evaluation of cadmium hexacianoferrate(III) as a microporous material

被引：28

作者：

Balmseda, J

Reguera, E

Gómez, A

Díaz, B

Autie, M

机构：

[1] Univ Havana, Inst Mat & Reagents, Havana 10400, Cuba

[2] Univ Havana, Fac Phys, Havana 10400, Cuba

[3] Natl Ctr Sci Res, Havana 6880, Cuba

来源：

MICROPOROUS AND MESOPOROUS MATERIALS | 2002年 / 54卷 / 03期

关键词：

cadmium ferricyanide; adsorption; Mossbauer; infrared; X-ray diffraction; adsorption isosteric heat;

D O I：

10.1016/S1387-1811(02)00389-X

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The properties of cadmium hexacyanoferrate(III), Cd-3[Fe(CN)(6)](2), as a microporous material were evaluated from adsorption data Of CO2, N-2 and water vapor. The adsorption isotherms were interpreted according to the Dubinin-Radushkevich and Dubinin-Astakhov models. The adsorbate-adsorbent interactions during the activation and the adsorption processes were monitored by XRD, IR and Mossbauer techniques where the adsorption of propanol, ethanol and diethyl ether was also considered. As a measure of the adsorbate-adsorbent interactions, calculations of the adsorption isosteric heats were also carried out. (C) 2002 Published by Elsevier Science Inc.

引用

页码：285 / 292

页数：8

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