New procedure to calculate the Hansen solubility parameters of polymers

被引:64
作者
Gharagheizi, Farhad [1 ]
机构
[1] Univ Tehran, Fac Engn, Dept Chem Engn, Tehran, Iran
关键词
adhesion; coatings; cohesion;
D O I
10.1002/app.23874
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The simplest experimental method to determine the Hansen solubility parameters (HSPs) for a polymer is to evaluate whether or not it dissolves in selected solvents. Those solvents dissolving the polymer will have HSPs closer to those of the polymer than those that do not. A computer program or graphical method can then be used to find the HSP for the polymer. In this work, an improved method for calculating the HSP of polymers, based on the Nelder-Mead optimization algorithm, is presented. The results of this program fit the data very well. (C) 2006 Wiley Periodicals, Inc. J Appl Polyrn Sci 103: 31-36, 2007
引用
收藏
页码:31 / 36
页数:6
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