A new precatalyst for the Suzuki reaction -: a pyridyl-bridged dinuclear palladium complex as a source of mono-ligated palladium(0)

被引：51

作者：

Beeby, A

Bettington, S

Fairlamb, IJS

Goeta, AE

Kapdi, AR

Niemelä, EH

Thompson, AL

机构：

[1] Univ Durham, Dept Chem, Durham DH1 3LE, England

[2] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England

来源：

NEW JOURNAL OF CHEMISTRY | 2004年 / 28卷 / 05期

关键词：

D O I：

10.1039/b401077a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A dinuclear pyridyl-bridged palladium complex, trans-(P,N)-[PdBr(mu-C5H4N-C-2,N)(PPh3)](2) 1, was obtained from material isolated from the Suzuki cross-coupling reaction of 2-bromopyridine with 2,4-diflorophenylboronic acid in the presence of catalytic (PPh3)(4)Pd. Complex 1 is an effective precatalyst for the Suzuki cross-coupling reactions of a variety organoboronic acids and aryl bromides, and represents a useful source of mono-ligated palladium(0), "(Ph3P)Pd(0)''.

引用

页码：600 / 605

页数：6

共 39 条

[1] SYNTHESIS AND RESOLUTION OF 1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE - A P-N CHELATING LIGAND FOR ASYMMETRIC CATALYSIS
ALCOCK, NW
BROWN, JM
HULMES, DI
[J]. TETRAHEDRON-ASYMMETRY, 1993, 4 (04) : 743 - 756
[2] The Cambridge Structural Database: a quarter of a million crystal structures and rising
Allen, FH
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2002, 58 (3 PART 1): : 380 - 388
[3] Identification of the effective palladium(0) catalytic species generated in situ from mixtures of Pd(dba)(2) and bidentate phosphine ligands. Determination of their rates and mechanism in oxidative addition
Amatore, C
Broeker, G
Jutand, A
Khalil, F
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (22) : 5176 - 5185
[4] Anionic Pd(0) and Pd(II) intermediates in palladium-catalyzed Heck and cross-coupling reactions
Amatore, C
Jutand, A
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2000, 33 (05) : 314 - 321
[5] Mechanistic and kinetic studies of palladium catalytic systems
Amatore, C
Jutand, A
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 576 (1-2) : 254 - 278
[6] STRUCTURE OF TRANS(P,N)-BIS(MU-PYRIDYL-C2,N)-BIS[CHLORO(TRIPHENYLPHOSPHINE)PALLADIUM(II)], [PD2CL2(C5H4N)2(P(C6H5)3)2]
ANDERSON, TA
BARTON, RJ
ROBERTSON, BE
VENKATASUBRAMANIAN, K
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1985, 41 (AUG) : 1171 - 1173
[7] [Anonymous], 1972, Inorg. Synth, DOI DOI 10.1002/9780470132449.CH23
[8] Solid-phase synthesis of isoxazoles using vinyl ethers as chameleon catches
Barrett, AGM
Procopiou, PA
Voigtmann, U
[J]. ORGANIC LETTERS, 2001, 3 (20) : 3165 - 3168
[9] BELL HC, 1974, TETRAHEDRON LETT, V15, P857
[10] Blettner CG, 1998, SYNLETT, P295

← 1 2 3 4 →