Multiproperty molecular materials: TTF-based conducting and magnetic molecular materials

被引：162

作者：

Ouahab, LN

Enoki, T

机构：

[1] Univ Rennes 1, CNRS, UMR 6511,Inst Chim Rennes, Grp Mat Mol,Lab Chim Solide & Inorgan Mol, F-35042 Rennes, France

[2] Tokyo Inst Technol, Dept Chem, Meguro Ku, Tokyo 1528551, Japan

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2004年 / 05期

关键词：

conducting materials; magnetic properties; through-space interactions; through-bond interactions;

D O I：

10.1002/ejic.200300869

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The chemistry and physics of molecule-based materials are exciting subjects, and due to potential applications this area is being extensively investigated. Considerable effort is currently being made to design and to investigate new materials involving interplay or synergy between multiple physical properties. This microreview examines materials combining magnetism and electrical properties. Some fundamental background material is covered, together with a discussion of constraints on the design of molecular materials with these physical properties. Some examples from the literature are then related, in order to illustrate the achievements in this area. (C) Wiley-VCH Verlag GmbH Co.

引用

页码：933 / 941

页数：9

共 58 条

[1] A RADICAL-ANION SALT OF 2,5-DIMETHYL-N,N'-DICYANOQUINONEDIIMINE WITH EXTREMELY HIGH ELECTRICAL-CONDUCTIVITY [J].

AUMULLER, A ;

ERK, P ;

KLEBE, G ;

HUNIG, S ;

VONSCHUTZ, JU ;

WERNER, HP .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1986, 25 (08) :740-741

[2] CATION RADICAL SALTS WITH MAGNETIC ANIONS - PREPARATION AND CHARACTERIZATION OF FECL4 SALTS OF TMTTF AND TMTSF [J].

BATAIL, P ;

OUAHAB, L ;

TORRANCE, JB ;

PYLMAN, ML ;

PARKIN, SSP .

SOLID STATE COMMUNICATIONS, 1985, 55 (07) :597-600

[3] Photo-induced electron transfer and magnetic switching in CoFe cyanides: Study of the metastable state [J].

Bleuzen, A ;

Lomenech, C ;

Dolbecq, A ;

Villain, F ;

Goujon, A ;

Roubeau, O ;

Nogues, M ;

Varret, F ;

Baudelet, F ;

Dartyge, E ;

Giorgetti, C ;

Gallet, JJ ;

Moulin, CCD ;

Verdaguer, M .

MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1999, 335 :965-974

[4] Synthesis and characterization of TTF-type precursors for the construction of conducting and magnetic molecular materials [J].

Bouguessa, S ;

Gouasmia, AK ;

Golhen, S ;

Ouahab, L ;

Fabre, JM .

TETRAHEDRON LETTERS, 2003, 44 (52) :9275-9278

[5] Synthesis, redox behaviour and X-ray structure of bis-TTF containing a pyridine unit as a potential building block in the construction of conducting magnetic materials [J].

Bouguessa, S ;

Hervé, K ;

Golhen, S ;

Ouahab, L ;

Fabre, JM .

NEW JOURNAL OF CHEMISTRY, 2003, 27 (03) :560-564

[6] Coexistence of ferromagnetism and metallic conductivity in a molecule-based layered compound [J].

Coronado, E ;

Galán-Mascarós, JR ;

Gómez-García, CJ ;

Laukhin, V .

NATURE, 2000, 408 (6811) :447-449

[7] THE CHEMISTRY OF MAGNETS [J].

DAY, P .

SCIENCE, 1993, 261 (5120) :431-432

[8] STRUCTURE AND PROPERTIES OF TRIS[BIS(ETHYLENEDITHIO)TETRATHIAFULVALENIUM]TETRACHLOROCOPPER(II) HYDRATE, (BEDT-TTF)3CUCL4.H2O - 1ST EVIDENCE FOR COEXISTENCE OF LOCALIZED AND CONDUCTION ELECTRONS IN A METALLIC CHARGE-TRANSFER SALT [J].

DAY, P ;

KURMOO, M ;

MALLAH, T ;

MARSDEN, IR ;

FRIEND, RH ;

PRATT, FL ;

HAYES, W ;

CHASSEAU, D ;

GAULTIER, J ;

BRAVIC, G ;

DUCASSE, L .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) :10722-10729

[9] A CONCEPT FOR THE SYNTHESIS OF 3-DIMENSIONAL HOMOMETALLIC AND BIMETALLIC OXALATE-BRIDGED NETWORKS [M(2)(OX)(3)](N) - STRUCTURAL, MOSSBAUER, AND MAGNETIC STUDIES IN THE FIELD OF MOLECULAR-BASED MAGNETS [J].

DECURTINS, S ;

SCHMALLE, HW ;

SCHNEUWLY, P ;

ENSLING, J ;

GUTLICH, P .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (21) :9521-9528

[10] CYANO-HALOGEN INTERACTIONS AND THEIR ROLE IN THE CRYSTAL-STRUCTURES OF THE 4-HALOBENZONITRILES [J].

DESIRAJU, GR ;

HARLOW, RL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (17) :6757-6764

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