Formation of InSb by annealing Sb2S3-In thin films

被引:9
作者
Nair, MTS [1 ]
Rodríguez-Lazcano, Y [1 ]
Nair, PK [1 ]
机构
[1] Univ Nacl Autonoma Mexico, Dept Solar Energy Mat, Ctr Invest Energia, Temixco 62580, Morelos, Mexico
关键词
chemical bath deposition; indium antimonide; antimony sulfide;
D O I
10.1016/S0022-0248(99)00472-8
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
We report a method to produce large area indium antimonide thin films through a reaction in solid state between thin films of Sb2S3 and In (Sb2S3 + 2 In --> 2 InSb + 3 S up arrow). A thin him of Sb2S3 with typically 0.2. mu m thickness is produced on glass substrate by chemical bath deposition at 10 degrees C using thiosulfatoantimonate(III) complex. Subsequently, a thin film of indium is deposited on the Sb2S3 film by thermal evaporation. Annealing the thin film stack of Sb2S3-In at 300 degrees C under nitrogen atmosphere produces the InSb thin film. The formation of this him is confirmed by X-ray diffraction studies. We discuss the optimization of the individual film thickness in the Sb2S3-In stack to produce a thin film of single-phase InSb or a heterostructure, Sb2S3-InSb. The electrical and optical properties of the films are presented. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:248 / 252
页数:5
相关论文
共 10 条
[1]   ELECTROCHEMICAL CODEPOSITION OF INDIUM AND ANTIMONY FROM A CHLOROINDATE MOLTEN-SALT [J].
CARPENTER, MK ;
VERBRUGGE, MW .
JOURNAL OF MATERIALS RESEARCH, 1994, 9 (10) :2584-2591
[2]   CdSe:In-In2O3 coating with n-type conductivity produced by air annealing of CdSe-In thin films [J].
Garcia, VM ;
George, PJ ;
Nair, MTS ;
Nair, PK .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (09) :2892-2895
[3]   Formation of a ZnSe:In2O3 heterostructure by air annealing ZnSe-In thin film [J].
García, VM ;
Nair, MTS ;
Nair, PK .
SEMICONDUCTOR SCIENCE AND TECHNOLOGY, 1999, 14 (04) :366-372
[4]   DOPING OF CHEMICALLY DEPOSITED INTRINSIC CDS THIN-FILMS TO N-TYPE BY THERMAL-DIFFUSION OF INDIUM [J].
GEORGE, PJ ;
SANCHEZ, A ;
NAIR, PK ;
NAIR, MTS .
APPLIED PHYSICS LETTERS, 1995, 66 (26) :3624-3626
[5]   Chemically deposited Sb2S3 and Sb2S3-CuS thin films [J].
Nair, MTS ;
Pena, Y ;
Campos, J ;
Garcia, VM ;
Nair, PK .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1998, 145 (06) :2113-2120
[6]   Formation of p-type Cu3BiS3 absorber thin films by annealing chemically deposited Bi2S3-CuS thin films [J].
Nair, PK ;
Huang, L ;
Nair, MTS ;
Hu, HL ;
Meyers, EA ;
Zingaro, RA .
JOURNAL OF MATERIALS RESEARCH, 1997, 12 (03) :651-656
[7]   Semiconductor thin films by chemical bath deposition for solar energy related applications [J].
Nair, PK ;
Nair, MTS ;
Garcia, VM ;
Arenas, OL ;
Pena, Y ;
Castillo, A ;
Ayala, IT ;
Gomezdaza, O ;
Sanchez, A ;
Campos, J ;
Hu, H ;
Suarez, R ;
Rincon, ME .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 1998, 52 (3-4) :313-344
[8]   Growth and characterization of AlAsySb1-y and InAsySb1-y thin films on GaAs and InAs substrates [J].
Nemeth, S ;
Grietens, B ;
Borghs, G .
THIN SOLID FILMS, 1998, 317 (1-2) :52-54
[9]  
Sze S.M., 1981, Physics of semiconductor devices, P849
[10]   Total low temperature plasma process for epitaxial growth of compound semiconductors on Si:InSb/Si [J].
Yamauchi, S ;
Hariu, T ;
Ohba, H ;
Sawamura, K .
THIN SOLID FILMS, 1998, 316 (1-2) :93-99