Metal oxo complexes as catalysts for the isomerisation of allylic alcohols

被引：38

作者：

Bellemin-Laponnaz, S ^{[1
]}

Le Ny, JP ^{[1
]}

机构：

[1] Univ Strasbourg, Inst Le Bel, UMR 7513 CNRS, Lab Chim Organomet & Catalyse, F-67070 Strasbourg, France

来源：

COMPTES RENDUS CHIMIE | 2002年 / 5卷 / 04期

关键词：

allylic alcohols; isomerisation; homogeneous catalysis; metal oxides;

D O I：

10.1016/S1631-0748(02)01371-1

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The 1,3-allylic rearrangement of allylic alcohols is an important transformation in organic synthesis and various methods for effecting such a transposition have been reported. This short review will focus on the development of transition metal oxo complexes as catalysts for the isomerisation of allylic alcohols. Mechanistic investigations are also discussed. (C) 2002 Academie des sciences / Editions scientifiques et medicales Elsevier SAS.

引用

页码：217 / 224

页数：8

共 25 条

[1] ON THE ALLYLIC REARRANGEMENTS IN METAL OXO COMPLEXES - MECHANISTIC AND CATALYTIC STUDIES ON MOO2(ALLYLOXO)2(CH3CN)2 AND ANALOGOUS COMPLEXES [J].