Flame pyrolysis - A preparation route for ultrafine pure gamma-Fe2O3 powders and the control of their particle size and properties

被引:86
作者
Grimm, S
Schultz, M
Barth, S
Muller, R
机构
[1] UNIV JENA,INST ANORGAN & ANALYT CHEM,D-07743 JENA,GERMANY
[2] INST PHYS HOCHTECHNOL,D-07743 JENA,GERMANY
关键词
D O I
10.1023/A:1018598927041
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Highly dispersed gamma-Fe2O3 powders with particle sizes down to 5 nm were directly synthesized by combustion of solutions of iron pentacarbonyl or iron(III) acetylacetonate in toluene in an oxyhydrogen flame. The particle size as well as other properties of the obtained powders can be controlled simply by varying the iron concentration in the starting solutions. Phase composition, morphological and magnetic properties of the powders were studied. The reasons for the formation of gamma-Fe2O3 are discussed by means of structure-chemical/kinetic considerations. The materials are interesting as recording materials, or ferrofluids, or for colour imaging and bioprocessing.
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页码:1083 / 1092
页数:10
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