Oxo-centered regular octahedral lanthanide clusters

被引：52

作者：

Zhang, DS ^{[1
]}

Ma, BQ

Jin, TZ

Gao, S

Yan, CH

Mak, TCW

机构：

[1] Peking Univ, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China

[2] Peking Univ, PKU HKU, Joint Lab Rare Earth Mat & Bioorgan Chem, Beijing 100871, Peoples R China

[3] Chinese Univ Hong Kong, Dept Chem, New Territories, Hong Kong, Peoples R China

来源：

NEW JOURNAL OF CHEMISTRY | 2000年 / 24卷 / 02期

关键词：

D O I：

10.1039/a908471a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of Ln(ClO4)(3), (Ln = Nd or Gd) with L-serine at pH 6.0 yielded the aqua hexanuclear clusters [Nd-6(mu(6)-O)(mu(3)-OH)(8)(H2O)(24)] (ClO4)(8) . 6 H2O (1) and [Gd-6(mu(6)-O)(mu(3)-OH)(8)(H2O)(24)] (ClO4)(8) . 6 H2O (2). They are isomorphons and comprised of a regular octahedron of 6 lanthanide ions encapsulating a mu(6)-O2- anion and capped by a mu(3)-OH group on each face. The structure can also be regarded as an oxo-centered octahedron embedded in a cube formed by 8 mu(3)-OH groups.

引用

页码：61 / 62

页数：2

共 24 条

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