Preparation and double-helix icosahedra structure of δ-Co2Zn15

被引：16

作者：

Boström, M ^{[1
]}

Lidin, S

机构：

[1] Stockholm Univ, Dept Struct Chem, S-10691 Stockholm, Sweden

[2] Stockholm Univ, Dept Inorgan Chem, S-10691 Stockholm, Sweden

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2002年 / 166卷 / 01期

关键词：

intermetallic compounds; zinc-cobalt; structure determination; synthesis design;

D O I：

10.1006/jssc.2002.9558

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first known example of a regular face-sharing icosahedra helix is presented in the novel crystal Structure Of delta-Co2Zn15, solved and refined from single-crystal X-ray and neutron powder diffraction data. The compound delta-Co2Zn15 is also the first example of an intermetallic compound crystallizing in the acentric hexagonal space group P6(2). The parameters from the single crystal refinement are a = 11.292(2) Angstrom, c = 7.750(l) Angstrom, Z = 4, and R-w = 0.025. (C) 2002 Elsevier Science (USA).

引用

页码：53 / 57

页数：5

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