A numerical approach to the voltammograms of the reduction of Prussian Blue films on ITO electrodes

被引：46

作者：

GarciaJareno, JJ ^{[1
]}

NavarroLaboulais, J ^{[1
]}

Vicente, F ^{[1
]}

机构：

[1] UNIV VALENCIA,FAC QUIM,DEPT QUIM FIS,E-46100 VALENCIA,SPAIN

来源：

ELECTROCHIMICA ACTA | 1997年 / 42卷 / 10期

关键词：

Prussian Blue films; ITO electrodes; ohmic drop; uncompensated resistance; multilayer model; voltammetric curves; simulation; finite difference;

D O I：

10.1016/S0013-4686(96)00302-7

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The uncompensated resistance, mainly due to the ITO electrode, modifies the shape of voltammetric curves of the system Prussian Blue reversible arrow Everitt's Salt films deposited on this transparent electrode. A numerical finite difference model which is able to explain the shape of these voltammetric curves is studied iii this paper. This model explains the dependence of voltammetric curves on the film thickness and uncompensated resistance. (C) 1997 Elsevier Science Ltd.

引用

页码：1473 / 1480

页数：8

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