Characterisation of commercially available electrochemical sensing platforms

被引:191
作者
Kadara, Rashid O. [1 ]
Jenkinson, Norman [1 ]
Banks, Craig E. [1 ]
机构
[1] Manchester Metropolitan Univ, Fac Sci & Engn, Sch Biol Chem & Hlth Sci, Div Chem & Mat, Manchester M1 5GD, Lancs, England
关键词
Electrochemical sensing platforms; Screen-printed electrodes; Characterisation; Outer-sphere electron transfer; Inner-sphere electron transfer; SCREEN-PRINTED ELECTRODES; EDGE-PLANE SITES; CARBON ELECTRODES; ELECTROCATALYSIS; BIOSENSORS; GRAPHITE;
D O I
10.1016/j.snb.2009.01.044
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Disposable screen-printed electrodes are routinely used for sensitive electro-analytical sensing but their reactivity and performance can greatly vary. In this paper we have electrochemically interrogated and characterised a range of commercially available screen-printed electrodes from Zensor. Dropsens and Kanichi with scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). Differing electrochemical reactivities are observed with the optimal electrochemical performance observed for Dropsens and certain Kanichi electrochemical platforms with the greatest reproducibility (relative standard deviation, %R.S.D.) observed with the electrodes from Kanichi. The effect of temperature and potential cycling the screen-printed electrochemical platforms is also explored. This report allows researchers to make informed decisions in sensor selection, design and development. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:556 / 562
页数:7
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