Naked Ga+ and In+ as pure acceptor ligands:: Structure and bonding of [GaPt(GaCp*)4][BArF]

被引：44

作者：

Buchin, Beatrice

Gemel, Christian

Cadenbach, Thomas

Fernandez, Israel

Frenking, Gernot

Fischer, Roland A.

机构：

[1] Univ Marburg, Fachbereich Chem, D-35032 Marburg, Germany

[2] Ruhr Univ Bochum, Lehrstuhl Organ Chem 2, D-44780 Bochum, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 31期

关键词：

density functional calculations; gallium; group; 13; elements; metalloids; platinum;

D O I：

10.1002/anie.200601007

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the buff: The reaction of [Pt(GaCp*)4] with the Ga + source [Ga2Cp*][BArF] (Cp* = C5Me5; BArF = B{C6H 3(3,5-CF3)2}4) leads to the title complex, which exhibits a naked gallium atom coordinated to a platinum center. DFT calculations reveal that the Ga+ ligand serves as a σ acceptor, and the Pt-Ga bond is additionally supported by strong π interactions. (Figure Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5207 / 5210

页数：4

共 40 条

[1]

[Anonymous], 2005, ANGEW CHEM

[2]

[Anonymous], 2004, ANGEW CHEM INT EDIT

[3] Kohn-Sham density functional theory: Predicting and understanding chemistry [J].