Stereoselective addition of sodium organyl chalcogenolates to alkynylphosphonates: synthesis of diethyl 2-(organyl)-2-(organochalcogenyl)vinylphosphonates

被引：48

作者：

Braga, AL ^{[1
]}

Alves, EF ^{[1
]}

Silveira, CC ^{[1
]}

de Andrade, LH ^{[1
]}

机构：

[1] Univ Fed Santa Maria, Dept Quim, BR-97105900 Santa Maria, RS, Brazil

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 02期

关键词：

D O I：

10.1016/S0040-4039(99)02044-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Organyl thiolate, selenolate or tellurolate anions reacted with alkynylphosphonates 1 to give diethyl 2-(organyl)-2-(organochalcogenyl)vinylphosphonates [beta-organochalcogenyl vinylphosphonates] 2 in satisfactory yields. The reaction was stereoselective, giving predominantly or exclusively the (Z)-stereoisomer. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：161 / 163

页数：3

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