Microgels: Old materials with new applications

被引:249
作者
Das, Mallika [1 ]
Zhang, Hong [1 ]
Kumacheva, Eugenia [1 ]
机构
[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada
关键词
polymer microgels; hybrid microgels; nanoparticles; microreactors; photonic materials; core-shell particles; microlenses; drug delivery;
D O I
10.1146/annurev.matsci.36.011205.123513
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
This review describes the most recent progress in the use of polymer multiresponsive microgels as central components of advanced, functional colloidal materials. Significant areas of development include the use of microgels as microreactors for templated synthesis of inorganic nanoparticles with predetermined properties, as optically active materials including lenses and photonic crystals, and as primary units in site-specific and controlled drug delivery systems. In the last category, both synthetic and biopolymeric microgels are discussed.
引用
收藏
页码:117 / 142
页数:26
相关论文
共 102 条
[1]   SELF-AGGREGATES OF HYDROPHOBIZED POLYSACCHARIDES IN WATER - FORMATION AND CHARACTERISTICS OF NANOPARTICLES [J].
AKIYOSHI, K ;
DEGUCHI, S ;
MORIGUCHI, N ;
YAMAGUCHI, S ;
SUNAMOTO, J .
MACROMOLECULES, 1993, 26 (12) :3062-3068
[2]   Nonclassical shapes of noble-metal colloids by synthesis in microgel nanoreactors [J].
Antonietti, M ;
Grohn, F ;
Hartmann, J ;
Bronstein, L .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (19) :2080-2083
[3]   PROPERTIES OF FRACTAL DIVINYLBENZENE MICROGELS [J].
ANTONIETTI, M ;
ROSENAUER, C .
MACROMOLECULES, 1991, 24 (11) :3434-3442
[4]   Doubly temperature sensitive core-shell microgels [J].
Berndt, I ;
Richtering, W .
MACROMOLECULES, 2003, 36 (23) :8780-8785
[5]  
Breulmann M, 2000, ADV MATER, V12, P502, DOI 10.1002/(SICI)1521-4095(200004)12:7<502::AID-ADMA502>3.0.CO
[6]  
2-#
[7]   Effects of polyether-modified poly(acrylic acid) microgels on doxorubicin transport in human intestinal epithelial Caco-2 cell layers [J].
Bromberg, L ;
Alakhov, V .
JOURNAL OF CONTROLLED RELEASE, 2003, 88 (01) :11-22
[8]   Smart microgel studies. Polyelectrolyte and drug-absorbing properties of microgels from polyether-modified poly(acrylic [J].
Bromberg, L ;
Temchenko, M ;
Hatton, TA .
LANGMUIR, 2003, 19 (21) :8675-8684
[9]  
BULONE D, 1990, PHYS J, V57, pA256
[10]   Highly branched poly(N-isopropylacrylamide)s with imidazole end groups prepared by radical polymerization in the presence of a styryl monomer containing a dithioester group [J].
Carter, S ;
Hunt, B ;
Rimmer, S .
MACROMOLECULES, 2005, 38 (11) :4595-4603