On water and in air: Fast and highly chemoselective transfer hydrogenation of aldehydes with iridium catalysts

被引：191

作者：

Wu, Xiaofeng ^{[1
]}

Liu, Jianke ^{[1
]}

Li, Xiaohong ^{[1
]}

Zanotti-Gerosa, Antonio ^{[1
]}

Hancock, Fred ^{[1
]}

Vinci, Daniele ^{[1
]}

Ruan, Jiwu ^{[1
]}

Xiao, Jianliang ^{[1
]}

机构：

[1] Univ Liverpool, Dept Chem, Liverpool Ctr Mat & Catalysis, Liverpool L69 7ZD, Merseyside, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 40期

关键词：

aldehydes; chemoselectivity; iridium; transfer hydrogenation; water;

D O I：

10.1002/anie.200602122

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Water as solvent: A fast, selective, and high-yielding transfer hydrogenation of a wide range of aldehydes is achieved using IrIII catalysts containing simple ethylene-diamine (en) ligands (see scheme; Ts = p-toluenesulfonyl, TOF = turnover frequency). This procedure is suitable for aldehydes with a wide range of functional groups. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

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收藏

页码：6718 / 6722

页数：5

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