Bis- and tris-(trichlorogermyl)gold(I) anions in their salts with cyclic dications [Au-2(Ph2PCH2PPh2)(2)](2+) and [Au-2(Ph2PCH2CH2PPh2)(2)](2+)

被引：27

作者：

Bauer, A ^{[1
]}

Schmidbaur, H ^{[1
]}

机构：

[1] TECH UNIV MUNICH,INST ANORGAN CHEM,D-85747 GARCHING,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1997年 / 07期

关键词：

D O I：

10.1039/a700891k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Insertion of GeCl2 into the Au-Cl bonds of [(AuCl)(2)(dppm)] or [(AuCl)(2)(dppe)] (dppm = Ph2PCH2PPh2 and dppe = Ph2PCH2-CH2PPh2) leads to the formation of bis(trichlorogermyl) complexes [Au-2(dppm/e)(2)](2+)[Au(GeCl3)(2)](2)(-), of which the dppm complex undergoes slow decomposition in solution to give [Au-2(dppm)(2)][Au(GeCl3)(3)], where the gold atom of the dianion is co-ordinated solely to three germanium atoms.

引用

页码：1115 / 1116

页数：2

共 20 条

[1] THE CRYSTAL AND MOLECULAR-STRUCTURE OF DICHLORO-1,2-BIS(DIPHENYLPHOSPHINO)-ETHANEDIGOLD(I) [J].

BATES, PA ;

WATERS, JM .

INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1985, 98 (02) :125-129

[2] THE GOLD-GERMANIUM BOND IN COORDINATION-COMPOUNDS OF THE TYPE (PH(3)P)(N)AUGECL3 WITH N=1,2 OR 3 [J].

BAUER, A ;

SCHIER, A ;

SCHMIDBAUR, H .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (17) :2919-2920

[3]

BAUER A, 1996, THESIS TU MUNICH

[4]

BAUER A, 1996, J AM CHEM SOC, V118, P2919

[5]

Cariati F, 1967, INORG CHIM ACTA, V1, P315, DOI [10.1016/S0020-1693(00)93194-3, DOI 10.1016/S0020-1693(00)93194-3]

[6] BIS(DIMETHYLPHENYLPHOSPHINE)TRICHLOROSTANNIOGOLD [J].

CLEGG, W .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1978, 34 (JAN) :278-281

[7] COMPLEXES OF TRICHLOROSTANNATE(2) WITH GROUP IB METALS [J].

DILTS, JA ;

JOHNSON, MP .

INORGANIC CHEMISTRY, 1966, 5 (11) :2079-&

[8] TRIPHENYLGERMYL COMPLEXES OF COPPER, SILVER, AND GOLD [J].

GLOCKLING, F ;

HOOTON, KA .

JOURNAL OF THE CHEMICAL SOCIETY, 1962, (JUL) :2658-&

[9]

GLOCKLING F, 1995, J CHEM SOC A, P2168

[10]

Johnson C. K., 1976, ORNL5138 ORTEP

← 1 2 →