Two-dimensional line-shape analysis of photon-echo signal

被引：50

作者：

Okumura, K ^{[1
]}

Tokmakoff, A

Tanimura, Y

机构：

[1] Inst Mol Sci, Div Theoret Studies, Okazaki, Aichi 4448585, Japan

[2] MIT, Dept Chem, Cambridge, MA 02139 USA

来源：

CHEMICAL PHYSICS LETTERS | 1999年 / 314卷 / 5-6期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0009-2614(99)01173-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We analyze the two-dimensional (2D) line shape obtained by 2D Fourier transforming the time-domain response of a photon-echo signal as a function of the two coherence periods, t(1) and t(3). The line shape obtained for a two-level system with homogeneous and inhomogeneous broadening is shown to be sensitive to the magnitude of both of these line-broadening mechanisms. It is shown that the ellipticity of the 2D line shape can be related to the ratio of homogeneous to inhomogeneous broadening. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：488 / 495

页数：8

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