Silica chloride in the presence of NaI is a useful system for the efficient and selective conversion of TMS, TBDMS and THP ethers into their corresponding iodides

被引：23

作者：

Firouzabadi, H ^{[1
]}

Iranpoor, N ^{[1
]}

Hazarkhani, H ^{[1
]}

机构：

[1] Shiraz Univ, Dept Chem, Coll Sci, Shiraz 71454, Iran

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 40期

关键词：

D O I：

10.1016/S0040-4039(02)01706-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Direct and highly selective conversion of benzylic, allylic and propargylic TMS, TBDMS and THP ethers into their corresponding iodides with the SiO2-Cl/NaI system is described. Reactions were conducted in CH3CN at room temperature. Aliphatic silyl and tetrahydropyranyl ethers remained almost intact under similar reaction conditions. (C) 2002 Published by Elsevier Science Ltd.

引用

页码：7139 / 7141

页数：3

共 32 条

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