Expeditious Synthesis of Contorted Hexabenzocoronenes

被引：55

作者：

Plunkett, Kyle N.

Godula, Kamil

Nuckolls, Colin ^{[1
]}

Tremblay, Noah

Whalley, Adam C.

Xiao, Shengxiong

机构：

[1] Columbia Univ, Dept Chem, New York, NY 10027 USA

来源：

ORGANIC LETTERS | 2009年 / 11卷 / 11期

基金：

美国国家科学基金会;

关键词：

HEXA-PERI-HEXABENZOCORONENES; SCHOLL REACTION;

D O I：

10.1021/ol9001834

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Contorted hexabenzocoronenes (HBCs) have been synthesized in an expedited manner utilizing a double Barton-Kellogg olefination reaction and a subsequent Scholl cyclization. The scope of both transformations was investigated using a series of pentacene quinones and double olefin precursors. The utility,of these reactions to help create functionalized and oligomeric HBCs in a rapid manner is demonstrated.

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页码：2225 / 2228

页数：4

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