Rhenium(IV) sulfide nanotubes

被引：98

作者：

Brorson, M ^{[1
]}

Hansen, TW ^{[1
]}

Jacobsen, CJH ^{[1
]}

机构：

[1] Haldor Topsoe Res Labs, DK-2800 Lyngby, Denmark

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 39期

关键词：

D O I：

10.1021/ja027084r

中图分类号：

O6 [化学];

学科分类号：

0703 [化学];

摘要：

Rhenium(IV) sulfide, ReS2, has been prepared with nanotubular morphology by carbon nanotube templating. A multiwall carbon nanotube material was impregnated with solutions of NH4ReO4 or ReCl5, followed by drying and sulfidation with H2S at 1000 °C. The composite material synthesized was characterized by high-resolution transmission electron microscopy and X-ray powder diffraction. Like previously described MS2 nanotube compounds, ReS2 has a layered structure consisting of S-M-S layers. Re atoms in ordinary ReS2 are octahedrally coordinated with S, and tetranuclear metal clusters are present as a consequence of metal-metal bonds. Copyright © 2002 American Chemical Society.

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页码：11582 / 11583

页数：2

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