On the estimate of blanks in differential pulse voltammetric techniques:: application to detection limits evaluation as recommended by IUPAC

被引：29

作者：

Blanc, R ^{[1
]}

González-Casado, A ^{[1
]}

Navalón, A ^{[1
]}

Vílchez, JL ^{[1
]}

机构：

[1] Univ Granada, Dept Analyt Chem, E-18071 Granada, Spain

来源：

ANALYTICA CHIMICA ACTA | 2000年 / 403卷 / 1-2期

关键词：

differential pulse voltammetry (DPV); anodic stripping voltammetry (ASV); blank signal; detection limit;

D O I：

10.1016/S0003-2670(99)00569-3

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A new method to obtain the signal associated with a blank in differential pulse voltammetry and stripping voltammetry techniques is applied. The signal assigned to the blank is obtained by direct integration of the background noise extrapolated values of the base-peak width at different concentrations in order to obtain the zero concentration. Detection limits more amenable to a statistical evaluation are thus implemented, as recommended by the International Union of Pure and Applied Chemistry (IUPAC). (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：117 / 123

页数：7

共 37 条

[1]

ABU AZ, 1998, FRESEN J ANAL CHEM, V360, P1

[2] Applications of adsorptive stripping voltammetry for the trace analysis of metals, pharmaceuticals and biomolecules [J].