Highly enantioselective catalytic carbon dioxide incorporation reaction: Nickel-catalyzed asymmetric carboxylative cyclization of bis-1,3-dienes

被引：176

作者：

Takimoto, M ^{[1
]}

Nakamura, Y ^{[1
]}

Kimura, K ^{[1
]}

Mori, M ^{[1
]}

机构：

[1] Hokkaido Univ, Grad Sch Pharmaceut Sci, Sapporo, Hokkaido 0600812, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 19期

关键词：

D O I：

10.1021/ja049506y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A method for nickel-catalyzed asymmetric carbon dioxide (CO2) incorporation via carbon-carbon bond formation was developed. In the presence of a catalytic amount of Ni(acac)2 and MeO-MOP, various bis-1,3-dienes reacted with CO2 (1 atm) and a diorganozinc reagent (Me2Zn or Ph2Zn) to afford cyclic carboxylic acids in good yields (71-100%) and with high enantioselectivities (90-96% ee). Copyright © 2003 American Chemical Society.

引用

页码：5956 / 5957

页数：2

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