Synthesis and structure of a tetrahydroxydisilane and a trihydroxycyclotrisiloxane with all the OH functions in cis position

被引：15

作者：

Ackerhans, C ^{[1
]}

Roesky, HW ^{[1
]}

Labahn, T ^{[1
]}

Magull, J ^{[1
]}

机构：

[1] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany

来源：

ORGANOMETALLICS | 2002年 / 21卷 / 17期

关键词：

D O I：

10.1021/om020345l

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of the tetrachlorodisilane R2Si2-Cl-4 (R = CH(SiMe3)(2)) with a mixture of H2O2/H2O/toluene resulted in the formation of the tetrahydroxy-disilane R2Si2(OH)(4). However the corresponding tetraaminodisilane R(2)S(i)2(NH2)(4) reacted under the same conditions to yield a trihydroxycyclotrisiloxane (RSi(OH)O)(3) (R = CH(SiMe3)(2)). The structures of both products were determined by X-ray crystallography. The latter structure is reminiscent of that of a calixarene with an inverse conic shape.

引用

页码：3671 / 3674

页数：4

共 33 条

[1] Halogenodisilanes:: Precursors for new disilane derivatives [J].

Ackerhans, C ;

Böttcher, P ;

Müller, P ;

Roesky, HW ;

Usón, I ;

Schmidt, HG ;

Noltemeyer, M .

INORGANIC CHEMISTRY, 2001, 40 (15) :3766-3773

[2]

Ackerhans C, 2000, EUR J INORG CHEM, P827

[3] HYDROGEN-BONDING IN ORGANOSILANETRIOLS - THE CRYSTAL-STRUCTURES OF TRIS(TRIMETHYLSILYL)SILYL-SILANETRIOLS AND TRIS(TRIMETHYLSILYL)-METHYL-SILANETRIOLS [J].

ALJUAID, SS ;

BUTTRUS, NH ;

DAMJA, RI ;

DEROUICHE, Y ;

EABORN, C ;

HITCHCOCK, PB ;

LICKISS, PD .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 371 (03) :287-295

[4] HYDROGEN-BONDING IN ORGANOSILANEDIOLS - THE CRYSTAL-STRUCTURE OF DI-O-TOLYSILANEDIOL [J].

ALJUAID, SS ;

EABORN, C ;

HITCHCOCK, PB ;

LICKISS, PD .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 362 (1-2) :17-22

[5] HYDROGEN-BONDING IN ORGANOSILANEDIOLS - THE CRYSTAL-STRUCTURE OF BIS(PENTAMETHYLCYCLOPENTADIENYL)SILANEDIOL [J].

ALJUAID, SS ;

EABORN, C ;

HITCHCOCK, PB ;

LICKISS, PD ;

MOHRKE, A ;

JUTZI, P .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 384 (1-2) :33-40

[6]

[Anonymous], 1966, ANWENDUNGEN SCHWINGU, DOI DOI 10.1007/978-3-642-85629-7

[7]

AUNER N, 1993, Z NATURFORSCH B, V48, P1625

[8]

Benner K, 1999, Z ANORG ALLG CHEM, V625, P541, DOI 10.1002/(SICI)1521-3749(199904)625:4<541::AID-ZAAC541>3.0.CO

[9]

2-A

[10] HYDROGEN-BONDING IN ORGANOSILICON HYDROXIDES - CRYSTAL-STRUCTURES OF DICYCLOHEXYLSILANEDIOL AND BIS(HYDROXYDIMETHYLSILYL)BIS(TRIMETHYLSILYL)METHANE [J].

BUTTRUS, NH ;

EABORN, C ;

HITCHCOCK, PB ;

LICKISS, PD ;

TAYLOR, AD .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 309 (1-2) :25-33

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