Chiral Lewis acid catalyzed ene-reactions

被引：105

作者：

Dias, LC ^{[1
]}

机构：

[1] Univ Estadual Campinas, UNICAMP, Inst Quim, BR-13083970 Campinas, SP, Brazil

来源：

CURRENT ORGANIC CHEMISTRY | 2000年 / 4卷 / 03期

关键词：

D O I：

10.2174/1385272003376274

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This review covers recent progress in the use of chiral Lewis acid catalysts in ene-reactions which involve carbonyl and imine compounds as enophiles. Chiral Lewis acid catalysts containing aluminum, titanium, ytterbium and copper are critically reviewed. Synthetic applications of recent systems are specifically discussed.

引用

页码：305 / 342

页数：38

共 105 条

[1] PARTIAL ASYMMETRIC INDUCTION IN ENE REACTION [J].

ACHMATOWICZ, O ;

SZECHNER, B .

JOURNAL OF ORGANIC CHEMISTRY, 1972, 37 (07) :964-+

[2] Mechanism of the carbonyl-ene reaction [J].

Achmatowicz, O ;

BialeckaFlorjanczyk, E .

TETRAHEDRON, 1996, 52 (26) :8827-8834

[3] Absorption of maleic acid-anhydride and azodicarbon acid-ester in simple unsaturated carbohydrogens. Information on the substitution processes in the allyl position. [J].

Alder, K ;

Pascher, F ;

Schmitz, A .

BERICHTE DER DEUTSCHEN CHEMISCHEN GESELLSCHAFT, 1943, 76 :27-53

[4] Enantiomeric impurities in chiral catalysts, auxiliaries and synthons used in enantioselective synthesis [J].

Armstrong, DW ;

Lee, JT ;

Chang, LW .

TETRAHEDRON-ASYMMETRY, 1998, 9 (12) :2043-2064

[5]

BELLER M, 1998, TRANSITION METALS FI

[6] CATALYTIC ASYMMETRIC CARBONYL-ENE REACTIONS [J].

BERRISFORD, DJ ;

BOLM, C .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (16) :1717-1719

[7]

Blaser HU, 1999, CHIRALITY, V11, P459, DOI 10.1002/(SICI)1520-636X(1999)11:5/6<459::AID-CHIR17>3.0.CO

[8]

2-N

[9]

BORZILLERI RM, 1995, SYNTHESIS-STUTTGART, P347

[10]

Bosnich B, 1998, ALDRICHIM ACTA, V31, P76

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