Size control of polyaniline nanoparticle by polymer surfactant

被引:61
作者
Kim, D [1 ]
Choi, J [1 ]
Kim, JY [1 ]
Han, YK [1 ]
Sohn, D [1 ]
机构
[1] Hanyang Univ, Dept Chem, Sungdong Ku, Seoul 133791, South Korea
关键词
D O I
10.1021/ma020162a
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The preparation of polyaniline (PANI) particles in a micellar solution composed of various molecular weight of hydrophobically en-capped poly (ethylene oxides) (HEUR) was discussed. The prepared PANI nanoparticles were emeraldine base (EB) form, which was proved by using Fourier transform infrared spectroscopy (FT-IR) and Ultraviolet (UV) spectroscopy. Results showed that the ringlike shape of PANI particles, crystallanity and conductivity strongly depend on the size of micelle.
引用
收藏
页码:5314 / 5316
页数:3
相关论文
共 17 条
[1]   AQUEOUS COLLOIDAL DISPERSIONS OF POLYANILINE FORMED BY USING POLY(VINYLPYRIDINE)-BASED STERIC STABILIZERS [J].
ARMES, SP ;
ALDISSI, M ;
AGNEW, S ;
GOTTESFELD, S .
LANGMUIR, 1990, 6 (12) :1745-1749
[2]   NOVEL COLLOIDAL DISPERSIONS OF POLYANILINE [J].
ARMES, SP ;
ALDISSI, M .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (02) :88-89
[3]   Ethyl(hydroxyethyl)cellulose stabilized polyaniline dispersions and destabilized nanoparticles therefrom [J].
Chattopadhyay, D ;
Banerjee, S ;
Chakravorty, D ;
Mandal, BM .
LANGMUIR, 1998, 14 (07) :1544-1547
[4]   Methyl cellulose stabilized polyaniline dispersions [J].
Chattopadhyay, D ;
Mandal, BM .
LANGMUIR, 1996, 12 (06) :1585-1588
[5]   Preparation of polyaniline nanoparticles in micellar solutions as polymerization medium [J].
Kim, BJ ;
Oh, SG ;
Han, MG ;
Im, SS .
LANGMUIR, 2000, 16 (14) :5841-5845
[6]   Emulsion polymerization process for organically soluble and electrically conducting polyaniline [J].
Kinlen, PJ ;
Liu, J ;
Ding, Y ;
Graham, CR ;
Remsen, EE .
MACROMOLECULES, 1998, 31 (06) :1735-1744
[7]   Synthesis and characterization of organically soluble polyaniline and polyaniline block copolymers [J].
Kinlen, PJ ;
Frushour, BG ;
Ding, Y ;
Menon, V .
SYNTHETIC METALS, 1999, 101 (1-3) :758-761
[8]   Annealing effects of dilute polyaniline/NMP solution [J].
Lee, YM ;
Kim, JH ;
Kang, JS ;
Ha, SY .
MACROMOLECULES, 2000, 33 (20) :7431-7439
[9]   Relations between the structure and electric conductivity of polyaniline protonated with camphorsulfonic acid [J].
Luzny, W ;
Banka, E .
MACROMOLECULES, 2000, 33 (02) :425-429
[10]   SURFACE-AREA MEASUREMENTS ON CONDUCTING POLYMER-INORGANIC OXIDE NANOCOMPOSITES [J].
MAEDA, S ;
ARMES, SP .
SYNTHETIC METALS, 1995, 73 (02) :151-155