Study of sorption, biodegradation and isomerization of HCH in stimulated sediment/water system

被引:115
作者
Wu, WZ
Xu, Y
Schramm, KW
Kettrup, A
机构
[1] TECH UNIV MUNICH,LEHRSTUHL OKOL CHEM & UMWELTANALYT,D-8000 MUNICH,GERMANY
[2] GSF FORSCHUNGSZENTRUM UMWELT & GESUNDHEIT,INST OKOL CHEM,D-85764 OBSCHLEISSHEIM,GERMANY
关键词
sorption; biodegradation; isomerization; HCH;
D O I
10.1016/S0045-6535(97)00266-X
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
This paper reported the sorption, biodegradation and isomerization of hexachlorocyclohexane (HCH) in laboratory sediment/water system under aerobic and anaerobic conditions, respectively. The effect of organic nutrient addition to the sorption of HCH was also investigated. It indicates that HCH is highly adsorbed on sediments under both conditions. During the tests, the biodegradation and isomerization of HCH were dramatically speeded up after organic nutrient additions, especially in the case of the observation under aerobic condition. It was found, beta-HCH was the most persistent in the environment, that is due to the isomerization of alpha-HCH in a big amount to beta-HCH, besides its chemical stability. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码:1887 / 1894
页数:8
相关论文
共 8 条
[1]   AEROBIC BIOMINERALIZATION OF ALPHA-HEXACHLOROCYCLOHEXANE IN CONTAMINATED SOIL [J].
BACHMANN, A ;
DEBRUIN, W ;
JUMELET, JC ;
RIJNAARTS, HHN ;
ZEHNDER, AJB .
APPLIED AND ENVIRONMENTAL MICROBIOLOGY, 1988, 54 (02) :548-554
[2]  
HARGRAVE B, 1976, INSTERACTIONS SEDIME, P6
[3]  
HUNB H, 1990, ENVIRON SCI TECHNOL, V24, P1349
[4]  
OXYNOS K, 1992, SPECIMEN BANKING, pP127
[5]   ORGANOCHLORINE CHEMICAL IN SKIN LIPIDS AS AN INDEX OF THEIR ACCUMULATION IN THE HUMAN-BODY [J].
SASAKI, K ;
ISHIZAKA, T ;
SUZUKI, T ;
TAKEDA, M ;
UCHIYAMA, M .
ARCHIVES OF ENVIRONMENTAL CONTAMINATION AND TOXICOLOGY, 1991, 21 (02) :190-194
[6]  
WANG JH, 1989, ENV CHEM, V8, P20
[7]   PCDD/F-s, PCBs, HCHs and HCB in sediments and soils of Ya-Er lake area in China: Results on residual levels and correlation to the organic carbon and particle size [J].
Wu, WZ ;
Schramm, KW ;
Henkelmann, B ;
Xu, Y ;
Yediler, A ;
Kettrup, A .
CHEMOSPHERE, 1997, 34 (01) :191-202
[8]  
YAO JR, 1987, ACTA ECOLOGICA SINIC, V6, P33