Supramolecular chirality of thermotropic liquid-crystalline folic acid derivatives

被引：167

作者：

Kato, T ^{[1
]}

Matsuoka, T

Nishii, M

Kamikawa, Y

Kanie, K

Nishimura, T

Yashima, E

Ujiie, S

机构：

[1] Univ Tokyo, Sch Engn, Dept Chem & Biotechnol, Bunkyo Ku, Tokyo 1138656, Japan

[2] Nagoya Univ, Grad Sch Engn, Dept Mol Design & Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan

[3] Shimane Univ, Dept Mat Sci, Matsue, Shimane 6908054, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 15期

关键词：

chirality; hydrogen bonds; liquid crystals materials; science; self-assembly;

D O I：

10.1002/anie.200353231

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Helical self-assembled columns form supramolecular chiral cubic and columnar liquid-crystalline phases (see picture). The complexation of hydrogen-bonded disks of folic acid derivatives that have oligo-(glutamic acid) moieties and lipophilic alkyl chains with nonchiral ions leads to the self-assembly of chiral Pm3n cubic and hexagonal columnar structures.

引用

页码：1969 / 1972

页数：4

共 61 条

[1] [Anonymous], ANGEW CHEM
[2] [Anonymous], ANGEW CHEM
[3] Auzély-Velty R, 1998, ANGEW CHEM INT EDIT, V37, P2511, DOI 10.1002/(SICI)1521-3773(19981002)37:18<2511::AID-ANIE2511>3.0.CO
[4] 2-0
[5] Rational design of the first spherical supramolecular dendrimers self-organized in a novel thermotropic cubic liquid-crystalline phase and the determination of their shape by X-ray analysis
Balagurusamy, VSK
Ungar, G
Percec, V
Johansson, G
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (07) : 1539 - 1555
[6] Supramolecular helical stacking of metallomesogens derived from enantiopure and racemic polycatenar oxazolines
Barberá, J
Cavero, E
Lehmann, M
Serrano, JL
Sierra, T
Vázquez, JT
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (15) : 4527 - 4533
[7] 2 FERROELECTRIC PHASES OF A COLUMNAR DIBENZOPYRENE
BOCK, H
HELFRICH, W
[J]. LIQUID CRYSTALS, 1995, 18 (03) : 387 - 399
[8] Design of thermotropic liquid crystals with micellar cubic mesophases: Amphiphilic N-(2,3-dihydroxypropyl)benzamides
Borisch, K
Diele, S
Goring, P
Kresse, H
Tschierske, C
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (19): : 2087 - 2089
[9] Chirality amplification in dynamic helical columns in water
Brunsveld, L
Lohmeijer, BGG
Vekemans, JAJM
Meijer, EW
[J]. CHEMICAL COMMUNICATIONS, 2000, (23) : 2305 - 2306
[10] Bushey ML, 2002, ANGEW CHEM INT EDIT, V41, P2828, DOI 10.1002/1521-3773(20020802)41:15<2828::AID-ANIE2828>3.0.CO

← 1 2 3 4 5 6 7 →