The effect of coordinated solvent ligands on the solid-state structures of compounds involving uranyl nitrate and Schiff bases

被引：53

作者：

Evans, DJ

Junk, PC

Smith, MK

机构：

[1] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia

[2] James Cook Univ N Queensland, Dept Chem, Townsville, Qld 4811, Australia

来源：

POLYHEDRON | 2002年 / 21卷 / 23期

关键词：

uranyl complexes; morphologies; Schiff base ligand;

D O I：

10.1016/S0277-5387(02)01182-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A range of solvent adducts of uranyl complexes of the Schiff base ligands salen (salen=N,N'-ethylenebis(salicylidenimine)) and salpn (=N,N'-propylenebis(salicylidenimine)) have revealed similar morphologies about the uranium centre. Subtle differences in hydrogen bonding arrays, types of solvents and conformation of the Schiff base ligands result in vastly different crystal packing motifs. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：2421 / 2431

页数：11

共 29 条

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[2] CRYSTAL AND MOLECULAR-STRUCTURE OF [NN'-ETHYLENEBIS(SALICYLIDENEIMINATO)](METHANOL)DIOXOURANIUM [J].