Infrared photodissociation spectroscopy of aniline+-(water)1.2 and aniline+-(methanol)1.2

被引：17

作者：

Honkawa, Y

Inokuchi, Y

Ohashi, K ^{[1
]}

Nishi, N

Sekiya, H

机构：

[1] Kyushu Univ, Fac Sci, Dept Chem, Fukuoka 8128581, Japan

[2] Kyushu Univ, Grad Sch Sci, Dept Mol Chem, Fukuoka 8128581, Japan

[3] Inst Mol Sci, Okazaki, Aichi 4448585, Japan

来源：

CHEMICAL PHYSICS LETTERS | 2002年 / 358卷 / 5-6期

关键词：

D O I：

10.1016/S0009-2614(02)00641-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Infrared photodissociation spectra of the aniline ion solvated by water and methanol molecules are measured in the 2600-3800 cm(-1) region. Substantially red-shifted and broadened transitions are distinctly observed at 3105 and 2915 cm(-1) for aniline(+)-(H2O)(1) and aniline(+)-(CH3OH)(1), respectively, and assigned to the stretching vibration of the hydrogen-bonded NH oscillator of the aniline(+) moiety. The spectra of aniline(+)-(H2O)(2) and aniline(-)-(CH3OH)(2) demonstrate a large perturbation to both of the NH oscillators, indicating that each NH bond is bound to a solvent molecule in the most stable structure. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：419 / 425

页数：7

共 19 条

[1] SPECTROSCOPIC STUDIES OF IONIC COMPLEXES AND CLUSTERS [J].