Telomerization of butadiene with methanol catalysed by cationic palladium complexes containing a bidentate phosphinoamino ligand

被引：22

作者：

Basato, M

Crociani, L

Benvenuti, F

Galletti, AMR

Sbrana, G

机构：

[1] Univ Padua, Dipartimento Chim Inorgan Met Organ & Analit, Ctr Studio Stabilita & Reattivita Composti Coordi, CNR, I-35131 Padua, Italy

[2] CNR, Ist Chim & Tecnol Mat Avanzati, I-35127 Padua, Italy

[3] Univ Pisa, Dipartimento Chim & Chim Ind, I-56126 Pisa, Italy

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1999年 / 145卷 / 1-2期

关键词：

telomerization; 1,3-butadiene; palladium catalysts; cationic palladium complexes; phosphinoamines;

D O I：

10.1016/S1381-1169(99)00154-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The cationic complexes [Pd(eta(3)-allyl){Ph2P(o-C6H4NMe2)}]PF6 (1) and [PdMe(PPh3){Ph2P(o-C6H4NMe2)}]CF3SO3 . C6H6 (2) catalyse, without any added phosphine, the telomerization reaction of 1,3-butadiene with methanol, showing high chemio- (> 95%) and regioselectivity towards the linear 1-methoxy-2,7-octadiene (> 93%). (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：313 / 316

页数：4

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