Changeover in a multimodal copper(II) catenate as monitored by EPR spectroscopy

被引:56
作者
Baumann, F
Livoreil, A
Kaim, W
Sauvage, JP
机构
[1] UNIV STUTTGART,INST ANORGAN CHEM,D-70550 STUTTGART,GERMANY
[2] UNIV STRASBOURG 1,INST LE BEL,URA 422 CNRS,LAB CHIM ORGANOMINERALE,F-67070 STRASBOURG,FRANCE
关键词
D O I
10.1039/a606282b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The electrochemically triggered rearrangement of a copper catenate is monitored by EPR spectroscopy;the initially generated tetrahedral copper(II) complex (with higher g-factor components and lower metal hyperfine splitting) is converted to a stable five-coordinate copper(II) species, within a few minutes at room temperature, in anhydrous MeCN.
引用
收藏
页码:35 / 36
页数:2
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