Changeover in a multimodal copper(II) catenate as monitored by EPR spectroscopy

被引：56

作者：

Baumann, F

Livoreil, A

Kaim, W

Sauvage, JP

机构：

[1] UNIV STUTTGART,INST ANORGAN CHEM,D-70550 STUTTGART,GERMANY

[2] UNIV STRASBOURG 1,INST LE BEL,URA 422 CNRS,LAB CHIM ORGANOMINERALE,F-67070 STRASBOURG,FRANCE

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 01期

关键词：

D O I：

10.1039/a606282b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The electrochemically triggered rearrangement of a copper catenate is monitored by EPR spectroscopy;the initially generated tetrahedral copper(II) complex (with higher g-factor components and lower metal hyperfine splitting) is converted to a stable five-coordinate copper(II) species, within a few minutes at room temperature, in anhydrous MeCN.

引用

页码：35 / 36

页数：2

共 28 条

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