We show our recent development on the epitaxial growth of oxide thin films by laser molecular beam epitaxy directed towards a possible new field of electro-photonics based on metal-oxide quantum structures. Examples of quantum structures include superlattices and tunnel junctions (2-dimensional), superconducting quantum wire arrays (1-dimensional), and quantum dots for photonic application (0-dimensional). For fabricating such structures, it is vitally important to prepare the substrate surface and to understand the growth dynamics. Such electro-phptonic functions as Josephson effect in high T-C tunnel junctions and excitonic UV-laser operation at room temperature in self-organized hexagonal nanocrystal ZnO films are presented.