Disilenyllithium from tetrasila-1,3-butadiene: A silicon analogue of a vinyllithium

被引：104

作者：

Ichinohe, M ^{[1
]}

Sanuki, K ^{[1
]}

Inoue, S ^{[1
]}

Sekiguchi, A ^{[1
]}

机构：

[1] Univ Tsukuba, Dept Chem, Tsukuba, Ibaraki 3058571, Japan

来源：

ORGANOMETALLICS | 2004年 / 23卷 / 13期

关键词：

D O I：

10.1021/om040056s

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of dilithiosilane, ((Bu2MeSi)-Bu-t)(2)SiLi2 (2), with 1,1,2,2-tetrachloro-1,2-dimesityldisilane produced the tetrasila-1,3-butadiene derivative ((Bu2MeSi)-Bu-t)(2)-Si=Si(Mes)(Mes)Si=Si((SiMeBu2)-Bu-t)(2) (3; Mes = 2,4,6-trimethylphenyl) as reddish purple crystals. The reaction of 3 with (BuLi)-Bu-t in THF produced 1, 1-bis(di-tert-butylmethylsilyl)-2-lithio-2-mesityldisilene (4) as red crystals, which is an sp(2)-type silyllithium species, by the reductive cleavage of the central Si-Si bond in 3.

引用

页码：3088 / 3090

页数：3

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