Influence of water and hydrocarbon processed in feedstream on the three-way behaviour of platinum-alumina catalysts

The influence of water and the nature of the hydrocarbon -methane, ethylene, propene and 1-butene- processed in the feedstream on the three-way behaviour of a ceria-modified alumina supported platinum catalyst is investigated. Experiments were carried out with static feedstreams with air-to-fuel ratios between 14.13 and 15.17 as well as with oxidizing-reducing cycled feedstreams simulating the real automobile exhaust mixture. Conclusions are drawn on the importance of water-gas shift and steam reforming reactions and their relationship with inhibition self-poisoning effects of carbon monoxide and/or hydrocarbons. Comparison of data of the prepared catalyst and those obtained at the same operational conditions with two commercial catalysts, with only platinum/alumina and platinum-rhodium/ceria-alumina respectively, allows confirmation of the effects of ceria and establishes the role of rhodium when added to the catalyst.