Historical perspectives on living anionic polymerization

被引：24

作者：

Smid, J ^{[1
]}

机构：

[1] SUNY Coll Environm Sci & Forestry, Fac Chem, Syracuse, NY 13210 USA

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2002年 / 40卷 / 13期

关键词：

ions and ion pairs; triple ions; mechanism; anionic polymerization; polymerization; styrene; living;

D O I：

10.1002/pola.10286

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A brief overview of the role that Dr. Michael Szwarc has played in unraveling the mechanism of living anionic polymerization is presented. Emphasis is placed on the different ionic species that control the propagation reaction in ether-type solvents. (C) 2002 Wiley Periodicals, Inc.

引用

页码：2101 / 2107

页数：7

共 43 条

[1]

ALVARINO JM, 1973, J POLYM SCI POLYM S, V42, P155

[2] ALTERNATIVE PATHS IN ANIONIC PROPAGATION OF ION PAIRS . EFFECT OF SOLVENT AND COUNTERION [J].

BHATTACH.DN ;

SMID, J ;

SZWARC, M .

JOURNAL OF PHYSICAL CHEMISTRY, 1965, 69 (02) :624-&

[3] STUDIES OF IONS AND ION PAIRS IN TETRAHYDROFURAN SOLUTION . ALKALI METAL SALTS OF TETRAPHENYLBORIDE [J].

BHATTACH.DN ;

LEE, CL ;

SMID, J ;

SZWARE, M .

JOURNAL OF PHYSICAL CHEMISTRY, 1965, 69 (02) :608-&

[4] REACTIVITIES AND CONDUCTIVITIES OF IONS AND ION PAIRS IN POLYMERIZATION PROCESSES [J].

BHATTACHARYYA, DN ;

LEE, CL ;

SMID, J ;

SZWARC, M .

JOURNAL OF PHYSICAL CHEMISTRY, 1965, 69 (02) :612-+

[5]

BOHM LL, 1974, BER BUNSEN PHYS CHEM, V78, P1064

[6]

BOHMLL, 1972, ADV POLYM SCI, V9, P1

[7]

BUNGE M, 1979, MAKROMOL CHEM, V180, P2637

[8] STUDIES OF SOLVATION PHENOMENA OF IONS AND ION PARIS IN DIMETHOXYETHANE AND TETRAHYDROFURAN [J].

CARVAJAL, C ;

TOLLE, KJ ;

SMID, J ;

SZWARC, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (24) :5548-&

[9] COMPLEXATION OF LITHIUM, SODIUM, AND POTASSIUM CARBANION PAIRS WITH POLYGLYCOL DIMETHY ETHERS (GLYMES - EFFECT OF CHAIN LENGTH AND TEMPERATURE [J].

CHAN, LL ;

WONG, KH ;

SMID, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (07) :1955-+

[10]

CHANG CJ, 1973, J AM CHEM SOC, V97, P2805

← 1 2 3 4 5 →