Synthesis of meso substituted porphyrins in air without solvents or catalysts

被引：56

作者：

Drain, CM

Gong, XC

机构：

[1] Department of Chemistry, Hunter College, City University of New York, New York, NY 10021

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 21期

关键词：

D O I：

10.1039/a704600f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

meso-Tetraarylporphyrins are synthesized from pyrrole and aryl aldehydes cleanly and efficiently in one step without solvents or catalysts by reactions at temperatures 10-15 degrees C above the boiling point of the starting aldehydes using air as oxidant.

引用

页码：2117 / 2118

页数：2

共 19 条

[1] MECHANISTIC INVESTIGATIONS OF PORPHYRIN SYNTHESES .I. PRELIMINARY STUDIES ON MS-TETRAPHENYLPORPHIN
ADLER, AD
SHERGALI.W
LONGO, FR
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1964, 86 (15) : 3145 - &
[2] A SIMPLIFIED SYNTHESIS FOR MESO-TETRAPHENYLPORPHIN
ADLER, AD
LONGO, FR
FINARELLI, JD
GOLDMACH.J
ASSOUR, J
KORSAKOF.L
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1967, 32 (02) : 476 - +
[3] ADLER AD, 1973, ANN NY ACAD SCI, V206
[4] PYRROMETHANES AND PORPHYRINS THEREFROM
ARSENAULT, GP
BULLOCK, E
MACDONALD, SF
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1960, 82 (16) : 4384 - 4389
[5] PHOTOGATING OF IONIC CURRENTS ACROSS LIPID BILAYERS - HYDROPHOBIC ION CONDUCTANCE BY AN ION CHAIN MECHANISM
DRAIN, CM
MAUZERALL, DC
[J]. BIOPHYSICAL JOURNAL, 1992, 63 (06) : 1556 - 1563
[6] AN EXAMPLE OF A WORKING MOLECULAR CHARGE SENSITIVE ION CONDUCTOR
DRAIN, CM
MAUZERALL, D
[J]. BIOELECTROCHEMISTRY AND BIOENERGETICS, 1990, 24 (02): : 263 - 268
[7] Self-assembly of a multi-porphyrin supramolecular macrocycle by hydrogen bond molecular recognition
Drain, CM
Russell, KC
Lehn, JM
[J]. CHEMICAL COMMUNICATIONS, 1996, (03) : 337 - 338
[8] SELF-ASSEMBLY OF SQUARE MULTIPORPHYRIN ARRAYS BY METAL-ION COORDINATION
DRAIN, CM
LEHN, JM
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (19) : 2313 - 2315
[9] THERMODYNAMIC ASPECTS OF PORPHYRIN SYNTHESIS AND BIOSYNTHESIS
GEORGE, P
[J]. ANNALS OF THE NEW YORK ACADEMY OF SCIENCES, 1973, 206 (OCT22) : 84 - 96
[10] COSMOCHEMICAL EVOLUTION OF LARGE ORGANIC-MOLECULES - ILLUSTRATIVE LABORATORY SIMULATIONS FOR PORPHYRINS
HODGSON, GW
[J]. ANNALS OF THE NEW YORK ACADEMY OF SCIENCES, 1972, 194 (MAY3) : 86 - &

← 1 2 →